MIKROSTRUKTUR SENG OKSIDA YANG DISINTESIS MENGGUNAKAN EKSTRAK DAUN ANTING-ANTING

Iis Nurhasanah; Nursanti Ajune Mukti; Safira Arta Paramita

doi:10.26877/jitek.v9i2/Nov.17270

MIKROSTRUKTUR SENG OKSIDA YANG DISINTESIS MENGGUNAKAN EKSTRAK DAUN ANTING-ANTING

Iis Nurhasanah, Nursanti Ajune Mukti, Safira Arta Paramita

Abstract

Cakupan aplikasi yang luas dari seng oksida telah meningkatkan produksi seng oksida menggunakan berbagai metode fisika dan metode kimia. Penggunaan bahan kimia berbahaya dalam produksi seng oksida, mendorong pemanfaatan bahan alam yang ramah lingkungan untuk mereduksi dampak lingkungan. Penelitian ini bertujuan untuk mensintesis seng oksida dengan memanfaatkan ekstrak daun anting-anting. Seng oksida disintesis menggunakan proses presipitasi dari campuran larutan seng nitrat dengan ekstrak daun anting-anting. Produk presipitasi dikalsinasi pada temperatur 500^oC selama 3 jam. Mikrostruktur produk presipitasi dianalisis menggunakan difraksi sinar-x dan scanning electron microscope. Pola difraksi sinar-x menunjukkan intensitas puncak-puncak difraksi yang tajam dan tinggi mengindikasikan pembentukan material kristalinitas tinggi. Analisis parameter-parameter struktur menghasilkan nilai yang bersesuaian dengan struktur wurtzite dari seng oksida. Partikel-partikel berbentuk bulat dengan ukuran 100 nm teramati pada citra electron microscope. Analisis mikrostruktur mengindikasikan bahwa seng oksida kristalin berhasil disintesis. Ekstrak daun anting-anting potensial sebagai bahan alami untuk sintesis oksida logam.

Keywords

seng oksida, struktur, daun anting-anting

Full Text:

PDF

References

Agarwal,H., Kumar, S.V., Rajeshkumar, S., 2017. “A review on green synthesis of zinc oxide na-noparticles – An eco-friendly approach”. Re-source-Efficient Technologies 3: 406–413

Darroudi, M, Sabouri. Z., Oskue, R.K., Zak, A.K., Kargar, H., Hamid, M.H.M.A., 2014. “Green chemistry approach for the synthesis of ZnO nanopowders and their cytotoxic effects”. Ce-ram. Int. 40(3): 4827-4831.

Eswari, K.M., Asaithambi, S., Karuppaiah, M., Sak-thivel, P., Balaji, V., Ponelakkia, D.K., Yuvak-kumar, R., Kumar, P., Vijayaprabhu, N., Ravi, G., 2022. “Green synthesis of ZnO nanoparti-cles using Abutilon Indicum and Tectona Grandis leaf extracts for evaluation of anti-diabetic, anti-inflammatory and in-vitro cyto-toxicity activities”. Ceram. Int. 48: 33624–33634.

Faheem, M., Siddiqi, H.M., Habib, A., Shahid, M., Afzal, A., 2022. “ZnO/Zn(OH)2 nanoparticles and self-cleaning coatings for the photocatalytic degradation of organic pollutants”. Front. Envi-ron. Sci, 10: 965925.

Kamarajan, G., Anburaj D.B., Porkalai, V., Muthuvel, A., Nedunchezhian, G. 2022. “Green synthesis of ZnO nanoparticles using Acalypha indica leaf extract and their photocatalyst degradation and antibacterial activity”. J. Indian Chem. Soc. 99:100695.

Karthik, S., Siva, P., Balu, K.S., Suriyaprabha, R., Ra-jendran, V., Maaza, M., 2017. “Acalypha indi-ca–mediated green synthesis of ZnO nanostructures under differential thermal treatment: Effect on textile coating, hydropho-bicity, UV resistance, and antibacterial activity”. Adv. Powder Technol. 28: 3184–3194.

Malik, A.Q., Mir, T.G., Kumar D., Mir, I.A., Rashid, A., Ayoub, M., Shukla, S., 2023. “A review on the green synthesis of nanoparticles, their bio-logical applications, and photocatalytic efficien-cy against environmental toxins”. Environ. Sci. Pollut. Res. 30: 69796–69823.

Prasad, A.R., Williams, L., Garvasis, J., Shamsheera K.O., Basheer, S.M., Kuruvilla, M., Joseph, A., 2021. “Applications of phytogenic ZnO nano-particles: A review on recent advancements”. J. Mol. Liq. 331: 115805.

Puthur, S., Raj, K.K., Anoopkumar, A.N., Rebello, S., Aneesh, E.M., 2020. “Acorus calamus mediated green synthesis of ZnO NPs: A novel nano antioxidant to future perspective”. Adv. Powder Technol. 31: 4679–4682.

Rohmaniah, S. & Nurhasanah, I., 2021. “Influence of the calcination temperature on the formation of precipitated ZnO:Ce nanocrystal by employ-ing ultrasound irradiation”. J. Phys. Conf. Ser. 1943: 012020.

Shaghaghi, Z., Mollaei, S., Amani-Ghadim, A.R., Abedini, Z., 2023. “Green synthesis of ZnO nanoparticles using the aqueous extract of Plat-anus orientalis: Structural characterization and photocatalytic activity”. Mater. Chem. Phys. 305: 12790.

Top, A. & Çetinkaya, H., 2015. “Zinc oxide and zinc hydroxide formation via aqueous precipitation: Effect of the preparation route and lysozyme addition”. Mater. Chem. Phys.167: 77-87.

Vijayakumar, S., Arulmozhi, P., Kumar, N., Sakthivel, B., Kumar , S.P., Praseetha, P.K., 2020. “Aca-lypha fruticosa L. leaf extract mediated synthe-sis of ZnO nanoparticles: Characterization and antimicrobial activities”. Mater. Today: Proc. 23: 73-80.

Visnukumar, P., Vivekanandhan, S., Misra M., Mo-hanty, A.K., 2018. “Recent advances and emerging opportunities in phytochemical syn-thesis of ZnO nanostructures”. Mater. Sci. Semi-cond. Process. 80: 143-161.

Xu, S. & Wang, Z.L., 2011. “One-Dimensional ZnO Nanostructures: Solution Growth and Functional Properties”. Nano Res. 2011, 4(11): 1013–1098.

Zelekew, O.A, Haitosa, H.H, Chen X., Wu, Y.N., 2023. “Recent progress on plant extract-mediated biosynthesis of ZnO-based nano-catalysts for environmental remediation: Chal-lenges and future outlooks”. Adv. Colloid Interface Sci. 317: 10293.

DOI: https://doi.org/10.26877/jitek.v9i2/Nov.17270